Kumar Raju Suresh, Osman Hasnah, Abdul Rahim Aisyah Saad, Goh Jia Hao, Fun Hoong-Kun
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 24;66(Pt 8):o2086-7. doi: 10.1107/S1600536810028357.
In the title compound, C(37)H(32)N(2)O(3), an intra-molecular O-H⋯N hydrogen bond generates a five-membered ring, producing an S(5) motif. The piperidone ring adopts a half-chair conformation. The two fused pyrrolidine rings have similar envelope conformations. The interplanar angles between the benzene rings A/B and C/D are 75.68 (7) and 30.22 (6)°, respectively. In the crystal structure, adjacent mol-ecules are inter-connected into chains propagating along the [010] direction via inter-molecular C-H⋯O hydrogen bonds. Further stabilization is provided by weak C-H⋯π inter-actions.
在标题化合物C(37)H(32)N(2)O(3)中,分子内的O-H⋯N氢键形成一个五元环,产生S(5) motif。哌啶酮环呈半椅式构象。两个稠合的吡咯烷环具有相似的信封式构象。苯环A/B和C/D之间的面间角分别为75.68 (7)°和30.22 (6)°。在晶体结构中,相邻分子通过分子间C-H⋯O氢键相互连接形成沿[010]方向延伸的链。弱C-H⋯π相互作用提供了进一步的稳定性。