Akriche Samah, Rzaigui Mohamed
Laboratoire de chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia.
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 20;65(Pt 1):m123. doi: 10.1107/S1600536808043018.
The title compound, (C(5)H(6)N(3)O(2))(2)[Cr(2)O(7)], consists of 2-amino-3-nitro-pyridinium cations and discrete dichromate anions linked together by N-H⋯O and C-H⋯O hydrogen bonds, forming thick layers parallel to (101). Layer cohesion is ensured by N-H⋯O hydrogen bonding in addition to electrostatic and van der Waals inter-actions, forming a three-dimensional framework. The dichromate anion is located on a twofold axis that passes through its bridging O atom.
标题化合物(C₅H₆N₃O₂)₂[Cr₂O₇]由2-氨基-3-硝基吡啶鎓阳离子和离散的重铬酸根阴离子通过N-H⋯O和C-H⋯O氢键连接在一起,形成平行于(101)的厚层。除了静电和范德华相互作用外,通过N-H⋯O氢键确保层间凝聚,形成三维框架。重铬酸根阴离子位于穿过其桥连O原子的二重轴上。