Akkurt Mehmet, Yılmaz Ulkü, Küçükbay Hasan, Gençaslan Mustafa, Büyükgüngör Orhan
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 20;65(Pt 1):o174-5. doi: 10.1107/S1600536808042761.
The title compound, C(26)H(26)N(2)S(2), was synthesized from bis-[1,3-bis-(3-phenyl-prop-yl)benzimidazolidine-2-yl-idene] and CS(2) in toluene. The mol-ecular structure is composed of a benzimidazole ring system with two phenyl-propyl substituents and a dithio-carboxyl-ate group in the 2-position. The benzimidazole unit is essentially planar, with a maximum atomic deviation of 0.008 (2) Å, and makes dihedral angles of 72.72 (10) and 27.62 (12)°, with the two phenyl rings. The dihedral angle between the two phenyl rings is 55.98 (15)°. The mol-ecular packing is stabilized by a C-H⋯S inter-molecular hydrogen-bonding inter-action and a C-H⋯π inter-action between a benzene H atom and the phenyl ring of a neighbouring mol-ecule.
标题化合物C(26)H(26)N(2)S(2)由双-[1,3-双-(3-苯基丙基)苯并咪唑啉-2-亚基]和CS(2)在甲苯中合成。分子结构由一个苯并咪唑环系组成，该环系在2位带有两个苯丙基取代基和一个二硫代羧酸酯基团。苯并咪唑单元基本呈平面状，最大原子偏差为0.008 (2) Å，与两个苯环的二面角分别为72.72 (10)°和27.62 (12)°。两个苯环之间的二面角为55.98 (15)°。分子堆积通过分子间C-H⋯S氢键相互作用以及苯H原子与相邻分子苯环之间的C-H⋯π相互作用得以稳定。
