Fun Hoong-Kun, Kia Reza, Maity Annada C, Maity Sibaprasad, Goswami Shyamaprosad
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 13;65(Pt 1):o97. doi: 10.1107/S1600536808041366.
In the title compound, C(6)H(6)Cl(2)N(2), intra-molecular N-H⋯Cl and C-H⋯Cl contacts generate five-membered rings, producing S(5) ring motifs. Pairs of inter-molecular N-H⋯N hydrogen bonds link neighbouring mol-ecules into dimers with R(2) (2)(8) ring motifs. In the crystal structure, these dimers are connected by N-H⋯Cl inter-actions and are packed into columns.
在标题化合物C₆H₆Cl₂N₂中,分子内的N—H⋯Cl和C—H⋯Cl接触形成五元环,产生S(5)环模式。分子间的N—H⋯N氢键对将相邻分子连接成具有R₂²(8)环模式的二聚体。在晶体结构中,这些二聚体通过N—H⋯Cl相互作用连接并堆积成列。