反式双（乙腈-κN）四水合钴（II）四氯合钴（II）酸盐
trans-Bis(acetonitrile-κN)tetra-aqua-cobalt(II) tetra-chloridocobaltate(II).
作者信息
Patroniak Violetta, Kubicki Maciej
机构信息
Department of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 10;65(Pt 2):m173-4. doi: 10.1107/S1600536809000750.
In the title complex, [Co(CH(3)CN)(2)(H(2)O)(4)][CoCl(4)], the Co(II) ions are octa-hedrally coordinated in the cation, with trans-disposed acetonitrile ligands, and tetra-hedrally coordinated in the anion. An extensive network of O-H(water)⋯Cl hydrogen bonds between cations and anions connects the ions into a three-dimensional network. The Co-Cl distances correlate with the number of hydrogen bonds accepted by the Cl atoms.
在标题配合物[Co(CH₃CN)₂(H₂O)₄][CoCl₄]中，Co(II)离子在阳离子中呈八面体配位，乙腈配体呈反式排列，在阴离子中呈四面体配位。阳离子和阴离子之间广泛的O-H（水）⋯Cl氢键网络将离子连接成三维网络。Co-Cl距离与Cl原子接受的氢键数量相关。
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