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（2Z）-5-（4-甲氧基苯基）-7-甲基-3-氧代-2-（3,4,5-三甲氧基苄叉基）-3,5-二氢-2H-噻唑并[3,2-a]嘧啶-6-羧酸乙酯

(2Z)-Ethyl 5-(4-methoxy-phen-yl)-7-methyl-3-oxo-2-(3,4,5-trimethoxy-benzyl-idene)-3,5-dihydro-2H-thia-zolo[3,2-a]pyrimidine-6-carboxyl-ate.

作者信息

Hou Zhao-Hui

机构信息

Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):o235. doi: 10.1107/S1600536808041019.

DOI:10.1107/S1600536808041019
PMID:21581852
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968379/
Abstract

In the title compound, C(27)H(28)N(2)O(7)S, the dihedral angles between the thia-zole ring and the mono- and tris-ubstituted benzene rings are 87.8 (2) and 17.9 (3)°, respectively. The dihydro-pyrimidine ring adopts a flattened boat conformation. In the crystal structure, π-π stacking occurs [centroid-centroid separation = 3.6611 (11) Å].

摘要

在标题化合物C(27)H(28)N(2)O(7)S中，噻唑环与单取代和三取代苯环之间的二面角分别为87.8 (2)°和17.9 (3)°。二氢嘧啶环呈扁平船式构象。在晶体结构中，存在π-π堆积作用[质心-质心间距 = 3.6611 (11) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5145/2968379/45d89ca7e6db/e-65-0o235-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5145/2968379/45d89ca7e6db/e-65-0o235-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5145/2968379/45d89ca7e6db/e-65-0o235-fig1.jpg

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