• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

1-(2,3,4,6-四-O-乙酰基-β-D-吡喃葡萄糖基)-3-硫代脲基硫脲一水合物

1-(2,3,4,6-Tetra-O-acetyl-β-d-gluco-pyranos-yl)-3-thio-ureidothio-urea monohydrate.

作者信息

Sun Weidong, Yao Jin, Bai Lifei, Wang Xiaoming

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):o242. doi: 10.1107/S1600536808043833.

DOI:10.1107/S1600536808043833
PMID:21581859
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968307/
Abstract

In the title compound, C(16)H(24)N(4)O(9)S(2)·H(2)O, the hexopyranosyl ring adopts a chair conformation ((4)C(1)), and the five substituents are in equatorial positions. In the crystal structure, extensive O-H⋯O, N-H⋯S and N-H⋯O hydrogen bonding leads to the formation of a three-dimensional network.

摘要

在标题化合物C(16)H(24)N(4)O(9)S(2)·H(2)O中，六吡喃糖环呈椅式构象（(4)C(1)），五个取代基处于平伏位置。在晶体结构中，广泛的O-H⋯O、N-H⋯S和N-H⋯O氢键导致形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8898/2968307/61d5e3aaedde/e-65-0o242-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8898/2968307/61d5e3aaedde/e-65-0o242-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8898/2968307/61d5e3aaedde/e-65-0o242-fig1.jpg

相似文献

1
1-(2,3,4,6-Tetra-O-acetyl-β-d-gluco-pyranos-yl)-3-thio-ureidothio-urea monohydrate.1-(2,3,4,6-四-O-乙酰基-β-D-吡喃葡萄糖基)-3-硫代脲基硫脲一水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):o242. doi: 10.1107/S1600536808043833.
2
Ranunculin.毛茛苷
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 4;66(Pt 10):o2503. doi: 10.1107/S1600536810034847.
3
1-[4-(2,3,4,6-Tetra-O-acetyl-β-d-allo-pyranos-yloxy)benzyl-idene]thio-semi-carbazide.1-[4-(2,3,4,6-四-O-乙酰基-β-D-阿洛吡喃糖氧基)亚苄基]硫代氨基脲
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):o679. doi: 10.1107/S1600536809007260.
4
3-Methyl-2,6-dinitro-N-(3-pent-yl)-4-[(2,3,4-tri-O-acetyl-β-d-xylos-yl)amino-methyl]-aniline.3-甲基-2,6-二硝基-N-(3-戊基)-4-[(2,3,4-三-O-乙酰基-β-D-木糖基)氨基甲基]-苯胺
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 31;64(Pt 8):o1623. doi: 10.1107/S1600536808023192.
5
3-Hydr-oxy-4-methoxy-benzaldehyde thio-semicarbazone hemihydrate.3-羟基-4-甲氧基苯甲醛硫代半卡巴腙半水合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):o2274-5. doi: 10.1107/S1600536808035617.
6
rac-6-Hy-droxy-4-(4-nitro-phen-yl)-5-(2-thienyl-carbon-yl)-6-(trifluoro-meth-yl)-3,4,5,6-tetra-hydro-pyrimidin-2(1H)-one monohydrate.
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 23;66(Pt 11):o2932-3. doi: 10.1107/S1600536810041589.
7
Crystal structure of 3,4-dimethyl 2-(tert-butyl-amino)-5-[2-oxo-4-(thio-morpholin-4-yl)-2H-chromen-3-yl]furan-3,4-di-carboxyl-ate ethyl acetate hemisolvate.3,4-二甲基-2-(叔丁基氨基)-5-[2-氧代-4-(硫代吗啉-4-基)-2H-色烯-3-基]呋喃-3,4-二羧酸乙酯乙酸乙酯半溶剂化物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Nov 28;71(Pt 12):o1003-4. doi: 10.1107/S2056989015021970. eCollection 2015 Dec 1.
8
(E)-2-[1-(1-Benzothio-phen-3-yl)ethyl-idene]hydrazinecarbothio-amide methanol hemisolvate.（E）-2-[1-（1-苯并噻吩-3-基）亚乙基]肼基甲硫酰胺甲醇半溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2008 May 10;64(Pt 6):o1022-3. doi: 10.1107/S160053680801297X.
9
Ethyl 4-hy-droxy-6-(4-hy-droxy-phen-yl)-4-trifluoro-methyl-2-sulfanyl-idene-1,3-diazinane-5-carboxyl-ate ethanol monosolvate.4-羟基-6-(4-羟基苯基)-4-三氟甲基-2-硫亚基-1,3-二嗪烷-5-羧酸乙酯乙醇单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1280-1. doi: 10.1107/S1600536811015376. Epub 2011 Apr 29.
10
1-Azido-ethoxy-2,3,4,6-tetra-O-acetyl-β-d-glucoside.1-叠氮基-乙氧基-2,3,4,6-四-O-乙酰基-β-D-葡萄糖苷
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):o2651. doi: 10.1107/S1600536809039737.

引用本文的文献

1
A new synthetic access to 2-N-(glycosyl)thiosemicarbazides from 3-N-(glycosyl)oxadiazolinethiones and the regioselectivity of the glycosylation of their oxadiazolinethione precursors.一种从 3-N-(糖基)恶二唑啉-2-硫酮到 2-N-(糖基)硫代氨基脲的新的合成途径，以及它们的恶二唑啉-2-硫酮前体的糖苷化区域选择性。
Beilstein J Org Chem. 2013;9:135-46. doi: 10.3762/bjoc.9.16. Epub 2013 Jan 21.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
An efficient route to pyrimidine nucleoside analogues by [4 + 2] cycloaddition reaction.通过[4 + 2]环加成反应合成嘧啶核苷类似物的有效途径。
J Org Chem. 2003 Oct 31;68(22):8583-7. doi: 10.1021/jo034709a.
3
O-ethyl and o-methyl n-(2,3,4,6-tetra-o-acetyl-beta-d-glucopyranosyl)thiocarbamate.O-乙基和O-甲基N-（2,3,4,6-四-O-乙酰基-β-D-吡喃葡萄糖基）硫代氨基甲酸酯
Acta Crystallogr C. 2001 May;57(Pt 5):566-8. doi: 10.1107/s0108270101000609. Epub 2001 May 15.
4
Carbohydrate biguanides as potential hypoglycemic agents.
J Med Chem. 1989 Sep;32(9):2110-6. doi: 10.1021/jm00129a015.