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全氢苯并咪唑-2-硫酮

Perhydro-benzimidazole-2-thione.

作者信息

Liu Yingchun, Li Xiaoyu

机构信息

Department of Biomedicine, Zhongshan Torch Polytechnic, Zhongshan 528436, Guangdong Province, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):o248. doi: 10.1107/S1600536808043894.

DOI:10.1107/S1600536808043894
PMID:21581864
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968239/
Abstract

The studied crystal of the title compound, C(7)H(12)N(2)S, is a racemic mixture of two isomers, viz. S,S and R,R. The two isomers share the same position on a mirror plane in the space group P2(1)/m; thus all atoms except one are disordered between two positions in a 1:1 ratio. Inter-molecular N-H⋯S hydrogen bonds link the mol-ecules into chains propagating in the [010] direction.

摘要

标题化合物C(7)H(12)N(2)S的研究晶体是两种异构体的外消旋混合物,即S,S和R,R。这两种异构体在空间群P2(1)/m的镜面上占据相同位置;因此,除一个原子外,所有原子都以1:1的比例在两个位置之间无序排列。分子间的N-H⋯S氢键将分子连接成沿[010]方向延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a0f/2968239/842e7320941c/e-65-0o248-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a0f/2968239/842e7320941c/e-65-0o248-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a0f/2968239/842e7320941c/e-65-0o248-fig1.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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Photodetector arrays directly assembled onto polymer substrates from aqueous solution.光电探测器阵列直接从水溶液组装到聚合物基板上。
J Am Chem Soc. 2007 Nov 21;129(46):14296-302. doi: 10.1021/ja073675b. Epub 2007 Oct 31.