Gowda B Thimme, Foro Sabine, Sowmya B P, Terao Hiromitsu, Fuess Hartmut
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 28;65(Pt 2):o389. doi: 10.1107/S1600536809002633.
In the structure of the title compound, C(14)H(12)ClNO, the N-H and C=O bonds are trans to each other. Furthermore, the C=O bond is syn to the ortho-methyl group in the benzoyl ring, similar to what is observed in 2-methyl-N-(4-methyl-phen-yl)benzamide and 2-methyl-N-phenyl-benzamide. The amide linkage (-NHCO-) makes dihedral angles of 36.9 (7) and 46.4 (5)° with the aniline and benzoyl rings, respectively, while the dihedral angle between the benzoyl and aniline rings is 83.1 (1)°. In the crystal structure, mol-ecules form chains running along the b axis through N-H⋯O hydrogen bonds.