2-甲基-N-苯基苯甲酰胺
2-Methyl-N-phenyl-benzamide.
作者信息
Gowda B Thimme, Foro Sabine, Sowmya B P, Fuess Hartmut
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 9;64(Pt 2):o383. doi: 10.1107/S1600536807068821.
In the structure of the title compound (NP2MBA), C(14)H(13)NO, the conformation of the C-O bond is syn to the ortho-methyl substituent in the benzoyl phenyl ring, while the N-H bond is anti to the ortho-methyl substituent. The structure of NP2MBA closely resembles that of 2-chloro-N-phenyl-benzamide, with similar bond parameters. The dihedral angle between the phenyl and benzoyl rings is 88.05 (5)°. Mol-ecules are linked into a chain through N-H⋯O hydrogen bonding.
在标题化合物（NP2MBA，C₁₄H₁₃NO）的结构中，C—O键的构象与苯甲酰基苯环上的邻甲基取代基呈顺式，而N—H键与邻甲基取代基呈反式。NP2MBA的结构与2-氯-N-苯基苯甲酰胺的结构非常相似，键参数相近。苯基和苯甲酰基环之间的二面角为88.05 (5)°。分子通过N—H⋯O氢键连接成链。
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