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(E)-3-(蒽-9-基)-1-(4-溴苯基)丙-2-烯-1-酮

(E)-3-(Anthracen-9-yl)-1-(4-bromo-phen-yl)prop-2-en-1-one.

作者信息

Suwunwong Thitipone, Chantrapromma Suchada, Karalai Chatchanok, Pakdeevanich Paradorn, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 31;65(Pt 2):o420-1. doi: 10.1107/S1600536809003122.

Abstract

In the title mol-ecule, C(23)H(15)BrO, the prop-2-en-1-one unit is planar and it makes dihedral angles of 20.9 (1) and 45.8 (1)°, respectively, with the 4-bromo-phenyl ring and the anthracene ring system. The interplanar angle between the 4-bromophenyl ring and the anthracene ring system is 35.52 (7)°. In the crystal structure, mol-ecules are linked into dimers by C-H⋯Br hydrogen bonds, and the dimers are linked into a zigzag network parallel to the bc plane by weak C-H⋯O hydrogen bonds and C-H⋯π inter-actions involving the central benzene ring of the anthracene ring system.

摘要

在标题分子C(23)H(15)BrO中,2-丙烯-1-酮单元是平面的,它与4-溴苯环和蒽环体系分别形成20.9 (1)°和45.8 (1)°的二面角。4-溴苯环与蒽环体系之间的面间角为35.52 (7)°。在晶体结构中,分子通过C-H⋯Br氢键连接成二聚体,二聚体通过弱C-H⋯O氢键和涉及蒽环体系中心苯环的C-H⋯π相互作用连接成平行于bc平面的锯齿状网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1600/2968141/b684549fe924/e-65-0o420-fig1.jpg

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