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μ-N，N，N′，N′-四-（2-吡啶甲基）-己烷-1，6-二胺]双-二氯锰（II）

μ-N,N,N',N'-Tetra-kis(2-pyridylmeth-yl)-hexane-1,6-diamine]bis-[dichlorido-manganese(II).

作者信息

Hwang In-Chul, Kim Nam-Ho, Ha Kwang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 4;65(Pt 3):m249. doi: 10.1107/S1600536809003663.

DOI:10.1107/S1600536809003663
PMID:21582043
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968529/
Abstract

The asymmetric unit of the title compound, [Mn(2)Cl(4)(C(30)H(36)N(6))], contains one-half of the formula unit; a centre of inversion is located at the mid-point of the mol-ecule. The two Mn(2+) ions are bridged by the dual tri-dentate N,N,N',N'-tetra-kis(2-pyridylmeth-yl)hexane-1,6-diamine ligand to form a dinuclear complex. Each Mn atom is five-coordinated in an approximately square-pyramidal geometry by three N atoms from the ligand and two Cl atoms. Inter-molecular π-π inter-actions between adjacent pyridine rings with a centroid-centroid distance of 3.576 (2) Å are reported.

摘要

标题化合物[Mn₂Cl₄(C₃₀H₃₆N₆)]的不对称单元包含半个化学式单元；一个对称中心位于分子的中点。两个Mn²⁺离子由双三齿N,N,N',N'-四(2-吡啶甲基)己烷-1,6-二胺配体桥联形成双核配合物。每个Mn原子通过来自配体的三个N原子和两个Cl原子以近似四方锥几何构型进行五配位。报道了相邻吡啶环之间质心距离为3.576(2) Å的分子间π-π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1ee/2968529/acdd28d98169/e-65-0m249-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1ee/2968529/68dd7f10be04/e-65-0m249-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1ee/2968529/acdd28d98169/e-65-0m249-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1ee/2968529/68dd7f10be04/e-65-0m249-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1ee/2968529/acdd28d98169/e-65-0m249-fig2.jpg

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本文引用的文献

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Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):m44. doi: 10.1107/S1600536807063313.
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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.