[N,N'-Bis(4-bromo-benzyl-idene)-2,2-di-methyl-propane-κN,N']iodidocopper(I).

The title compound, [CuI(C(19)H(20)Br(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.7 (3)°. A six-membered chelate ring in a chair conformation is formed by the coordination of the imine N atoms of the bidentate ligand to the Cu(I) atom. This conformation is required by the crystallographic mirror symmetry. The inter-planar angle between the benzene rings is 74.85 (19)°. The crystal structure exhibits weak inter-molecular C-H⋯π inter-actions, which link the mol-ecules into chains along the b axis.