• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

[二（4-溴苄叉基）-2,2-二甲基丙烷-κN,N']碘化亚铜

[N,N'-Bis(4-bromo-benzyl-idene)-2,2-di-methyl-propane-κN,N']iodidocopper(I).

作者信息

Kia Reza, Fun Hoong-Kun, Kargar Hadi

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 18;65(Pt 3):m289. doi: 10.1107/S1600536809005078.

DOI:10.1107/S1600536809005078
PMID:21582073
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968488/
Abstract

The title compound, [CuI(C(19)H(20)Br(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.7 (3)°. A six-membered chelate ring in a chair conformation is formed by the coordination of the imine N atoms of the bidentate ligand to the Cu(I) atom. This conformation is required by the crystallographic mirror symmetry. The inter-planar angle between the benzene rings is 74.85 (19)°. The crystal structure exhibits weak inter-molecular C-H⋯π inter-actions, which link the mol-ecules into chains along the b axis.

摘要

标题化合物[CuI(C₁₉H₂₀Br₂N₂)]位于一个晶体学镜面平面上。铜中心周围的配位呈扭曲的三角平面，咬角为94.7 (3)°。双齿配体的亚胺N原子与Cu(I)原子配位形成了一个椅式构象的六元螯合环。这种构象是由晶体学镜面对称性所要求的。苯环之间的面间角为74.85 (19)°。晶体结构表现出弱的分子间C—H⋯π相互作用，这些相互作用将分子沿b轴连接成链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/feb4/2968488/e1b9dfb11040/e-65-0m289-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/feb4/2968488/7a59a1d14c25/e-65-0m289-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/feb4/2968488/e1b9dfb11040/e-65-0m289-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/feb4/2968488/7a59a1d14c25/e-65-0m289-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/feb4/2968488/e1b9dfb11040/e-65-0m289-fig2.jpg

相似文献

1
[N,N'-Bis(4-bromo-benzyl-idene)-2,2-di-methyl-propane-κN,N']iodidocopper(I).[二（4-溴苄叉基）-2,2-二甲基丙烷-κN,N']碘化亚铜
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 18;65(Pt 3):m289. doi: 10.1107/S1600536809005078.
2
[N,N'-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κN,N']iodidocopper(I).[双（4-氯亚苄基）-2,2-二甲基丙烷-1,3-二胺-κN,N']碘化亚铜
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 17;65(Pt 2):m197. doi: 10.1107/S160053680900107X.
3
N,N'-Bis(4-bromo-benzyl-idene)-2,2-dimethyl-propane-1,3-diamine.N,N'-双(4-溴-亚苄基)-2,2-二甲基丙烷-1,3-二胺
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 14;65(Pt 4):o747. doi: 10.1107/S1600536809008113.
4
Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)hydrazinecarbodithio-ato-κN',S]copper(II).双[苄基 N'-(3-苯基-丙-2-烯基亚甲基)肼基二硫代甲酸根合-κN',S]铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 25;64(Pt 2):m416-7. doi: 10.1107/S1600536808002262.
5
{4,4'-Dimethyl-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}copper(II) monohydrate.一水合{4,4'-二甲基-2,2'-[2,2-二甲基丙烷-1,3-二亚基双(腈基亚甲基)]二酚根合}铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1172. doi: 10.1107/S1600536812034502. Epub 2012 Aug 11.
6
fac-[N,N'-Bis(3-chloro-2-fluoro-benzyl-idene)ethyl-enediamine]bromido-tri-carbonyl-rhenium(I).面式-[N,N'-双(3-氯-2-氟-亚苄基)乙二胺]溴代三羰基铼(I)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 14;65(Pt 2):m192-3. doi: 10.1107/S1600536809001044.
7
catena-Poly[[[bis-[2,2'-(propane-1,3-diyl-dithio)bis-(1,3,4-thia-diazole)-κN]copper(II)]-bis-[μ-2,2'-(propane-1,3-diyldithio)bis-(1,3,4-thia-diazole)-κN:N]] bis-(perchlorate)].链状聚[[[双-[2,2'-(丙烷-1,3-二硫基)双-(1,3,4-噻二唑)-κN]铜(II)]-双-[μ-2,2'-(丙烷-1,3-二硫基)双-(1,3,4-噻二唑)-κN:N]]双-(高氯酸盐)]
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 28;65(Pt 3):m349-50. doi: 10.1107/S1600536809006722.
8
Crystal structure of (E)-N-(3,4-di-meth-oxy-benzyl-idene)morpholin-4-amine.（E）-N-（3,4-二甲氧基-亚苄基）吗啉-4-胺的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Aug 1;70(Pt 9):o935. doi: 10.1107/S160053681401678X. eCollection 2014 Sep 1.
9
N,N'-Bis(5-bromo-2-hydroxy-benzyl-idene)-2,2-dimethylpropane-1,3-diamine.N,N'-双（5-溴-2-羟基-亚苄基）-2,2-二甲基丙烷-1,3-二胺
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 6;64(Pt 10):o1895-6. doi: 10.1107/S160053680802816X.
10
N,N'-Bis(4-bromo-2-fluoro-benzyl-idene)ethane-1,2-diamine.N,N'-双(4-溴-2-氟苄叉基)乙烷-1,2-二胺
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 13;64(Pt 10):o1941-2. doi: 10.1107/S1600536808029000.

本文引用的文献

1
[N,N'-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine-κN,N']iodidocopper(I).[双（4-氯亚苄基）-2,2-二甲基丙烷-1,3-二胺-κN,N']碘化亚铜
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 17;65(Pt 2):m197. doi: 10.1107/S160053680900107X.
2
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.