聚[[三-[μ-2,2'-（丁烷-1,4-二硫基）双-（1,3,4-噻二唑）-κN:N]铜（II）]双-（高氯酸盐）]
Poly[[tris-[μ-2,2'-(butane-1,4-diyl-dithio)bis-(1,3,4-thia-diazole)-κN:N]copper(II)] bis-(perchlorate)].
作者信息
Hu Pu-Zhou, Qin Jian-Hua, Wang Jian-Ge
机构信息
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 21;65(Pt 3):m307. doi: 10.1107/S1600536809005625.
In the title compound, {Cu(C(8)H(10)N(4)S(4))(3)(2)}(n), the Cu(II) atom is located on a threefold inversion axis coordinated by six N atoms of symmetry-equivalent 2,2'-(butane-1,4-diyl-dithio)bis-(1,3,4-thia-diazole) ligands in a slightly distorted octa-hedral geometry. Adjacent Cu(II) atoms are linked by the bridging bidentate thia-diazole ligands, which are situated about inversion centers. This leads to the formation of a three-dimensional network structure.
在标题化合物{Cu(C₈H₁₀N₄S₄)₃₂}ₙ中，Cu(II)原子位于一个三重反演轴上，由对称等效的2,2'-（丁烷-1,4-二硫基）双-（1,3,4-噻二唑）配体的六个N原子配位，呈轻微扭曲的八面体几何构型。相邻的Cu(II)原子通过桥连双齿噻二唑配体相连，这些配体位于反演中心周围。这导致形成了三维网络结构。
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