Su Yu, He Chuan, Sun Zhi-Zhong, Hou Guang-Feng, Gao Jin-Sheng
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 25;65(Pt 3):m313-4. doi: 10.1107/S1600536809005881.
In the title compound, {Co(C(10)H(14)N(4))(2)(H(2)O)(2)(2)}(n), the Co(II) ion lies on an inversion center and is six-coordinated in an octa-hedral environment by four N atoms from four different 1,1'-butane-1,4-diyldiimidazole ligands and two O atoms from the two water mol-ecules. The Co(II) atoms are bridged by ligands, generating a two-dimensional (4,4)-network. Adjacent fishnet planes are linked to the nitrate anions via O-H⋯O hydrogen bonds, forming a three-dimensional supra-molecular structure.
在标题化合物{Co(C₁₀H₁₄N₄)₂(H₂O)₂₂}ₙ中,Co(II)离子位于一个对称中心上,在八面体环境中通过来自四个不同的1,1'-丁烷-1,4-二亚基二咪唑配体的四个N原子和来自两个水分子的两个O原子进行六配位。Co(II)原子由配体桥连,形成二维(4,4)网络。相邻的渔网平面通过O—H⋯O氢键与硝酸根阴离子相连,形成三维超分子结构。