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聚[[[二水合钴（II）]-双-[μ(2)-1,1'-（丁烷-1,4-二基）二咪唑-κN:N]]硝酸酯]

Poly[[[diaqua-cobalt(II)]-bis-[μ(2)-1,1'-(butane-1,4-di-yl)diimidazole-κN:N]] dinitrate].

作者信息

Su Yu, He Chuan, Sun Zhi-Zhong, Hou Guang-Feng, Gao Jin-Sheng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 25;65(Pt 3):m313-4. doi: 10.1107/S1600536809005881.

DOI:10.1107/S1600536809005881
PMID:21582089
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968530/
Abstract

In the title compound, {Co(C(10)H(14)N(4))(2)(H(2)O)(2)(2)}(n), the Co(II) ion lies on an inversion center and is six-coordinated in an octa-hedral environment by four N atoms from four different 1,1'-butane-1,4-diyldiimidazole ligands and two O atoms from the two water mol-ecules. The Co(II) atoms are bridged by ligands, generating a two-dimensional (4,4)-network. Adjacent fishnet planes are linked to the nitrate anions via O-H⋯O hydrogen bonds, forming a three-dimensional supra-molecular structure.

摘要

在标题化合物{Co(C₁₀H₁₄N₄)₂(H₂O)₂₂}ₙ中，Co(II)离子位于一个对称中心上，在八面体环境中通过来自四个不同的1,1'-丁烷-1,4-二亚基二咪唑配体的四个N原子和来自两个水分子的两个O原子进行六配位。Co(II)原子由配体桥连，形成二维(4,4)网络。相邻的渔网平面通过O—H⋯O氢键与硝酸根阴离子相连，形成三维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68eb/2968530/70ac14f11c8d/e-65-0m313-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68eb/2968530/803bd4e2feb5/e-65-0m313-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68eb/2968530/79d26450cc43/e-65-0m313-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68eb/2968530/70ac14f11c8d/e-65-0m313-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68eb/2968530/803bd4e2feb5/e-65-0m313-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68eb/2968530/79d26450cc43/e-65-0m313-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68eb/2968530/70ac14f11c8d/e-65-0m313-fig3.jpg

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本文引用的文献

1
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Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 4;64(Pt 5):m628. doi: 10.1107/S160053680800874X.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
A porous supramolecular architecture from a copper(II) coordination polymer with a 3D four-connected 8(6) net.一种具有三维四连接8(6)网络结构的铜(II)配位聚合物形成的多孔超分子结构。
Inorg Chem. 2003 Nov 17;42(23):7531-4. doi: 10.1021/ic034846q.