Booth K Victoria, Jenkinson Sarah F, Fleet George W J, Watkin David J
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 21;65(Pt 3):o570. doi: 10.1107/S1600536809005777.
X-ray crystallography unequivocally confirmed the stereochemistry of the C atom at position 2 in the carbon scaffold of the title mol-ecule, C(10)H(18)O(4). The pyran-ose ring exists in a chair conformation with the methyl group on the C atom in the 2 position in an equatorial configuration. The absolute stereochemistry was determined from the starting material. The crystal structure consists of O-H⋯O hydrogen-bonded chains of mol-ecules running parallel to the b axis.
X射线晶体学明确证实了标题分子C(10)H(18)O(4)碳骨架中2位碳原子的立体化学结构。吡喃糖环呈椅式构象,2位碳原子上的甲基处于平伏构型。绝对立体化学结构由起始原料确定。晶体结构由平行于b轴的分子间O-H⋯O氢键链组成。