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双（2,2':6',2''-三联吡啶）钴（II）双（三氰基甲烷化物）

Bis(2,2':6',2''-terpyridine)cobalt(II) bis-(tricyano-methanide).

作者信息

Luo Jun, Zhang Xin-Rong, Qiu Li-Juan, Liu Bao-Shu, Zhang Zhi-Yan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 28;65(Pt 4):m455-6. doi: 10.1107/S160053680901071X.

DOI:10.1107/S160053680901071X
PMID:21582390
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968836/
Abstract

The title complex, Co(C(15)H(11)N(3))(2)(2), is built up from discrete Co(terpy)(2) cations (terpy is 2,2':6',2''-terpyridine) and C(CN)(3) anions. In the cation, the Co(II) atom is coordinated by two terpy mol-ecules, giving a distorted octa-hedral geometry. The tricyano-methanide anions are not directly coordinated to the Co(II) atom, but some weak C-H⋯N hydrogen bonds involving the terminal N atoms of the tricyaomethanide ions and the terpyridine H atoms link anions and cations building a three-dimensional network.

摘要

标题配合物Co(C₁₅H₁₁N₃)₂₂由离散的[Co(terpy)₂]²⁺阳离子（terpy为2,2':6',2''-三联吡啶）和[C(CN)₃]⁻阴离子组成。在阳离子中，Co(II)原子由两个terpy分子配位，形成扭曲的八面体几何构型。三氰基甲烷阴离子不直接与Co(II)原子配位，但一些涉及三氰基甲烷离子末端N原子和三联吡啶H原子的弱C-H⋯N氢键将阴离子和阳离子连接起来，构建了一个三维网络。

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本文引用的文献

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