Xiao Zhu-Ping, Peng Xiao-Chun, Wang Ying-Chun
College of Chemistry & Chemical Engineering, Jishou University, Jishou 416000, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):o672. doi: 10.1107/S1600536809007089.
In the title compound, C(20)H(18)N(4)O(2), the amino-acrylamide group makes a dihedral angles of 4.0 (1)° with the amino-bound pyridyl ring and 15.66 (12)° with the amide-bound pyridyl ring. The dihedral angle between the amino-acrylamide group and the pendant 4-methoxy-phenyl group is 71.22 (9)°. In the crystal structure, N-H⋯N hydrogen bonds and C-H⋯O and C-H⋯N inter-actions help to establish the packing. Intra-molecular C-H⋯O and C-H⋯(N,O) contacts also occur.
在标题化合物C₂₀H₁₈N₄O₂中,氨基丙烯酰胺基团与氨基连接的吡啶环形成的二面角为4.0(1)°,与酰胺连接的吡啶环形成的二面角为15.66(12)°。氨基丙烯酰胺基团与悬垂的4-甲氧基苯基之间的二面角为71.22(9)°。在晶体结构中,N-H⋯N氢键以及C-H⋯O和C-H⋯N相互作用有助于形成堆积。分子内也存在C-H⋯O和C-H⋯(N,O)接触。