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7α-甲氧基羰基-6,7,8,14-四氢-6,14-内乙烯基蒂巴因

7α-Methoxy-carbonyl-6,7,8,14-tetra-hydro-6,14-endo-ethenothebaine.

作者信息

Odabaşoğlu Mustafa, Yavuz Serkan, Pamir Ozgür, Yıldırır Yılmaz, Büyükgüngör Orhan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):o864. doi: 10.1107/S1600536809009362.

DOI:10.1107/S1600536809009362
PMID:21582578
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968994/
Abstract

In the mol-ecule of the title compound, C(23)H(27)NO(5), the furan ring adopts an envelope conformation. Intra-molecular C-H⋯O inter-actions result in the formation of S(5) and S(6) motifs. In the crystal structure, weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules through C(6) and C(8) chains along the [100] and [010] directions, generating a two-dimensional network.

摘要

在标题化合物C(23)H(27)NO(5)的分子中，呋喃环呈信封构象。分子内C—H⋯O相互作用导致形成S(5)和S(6) motif。在晶体结构中，弱的分子间C—H⋯O氢键沿[100]和[010]方向通过C(6)和C(8)链连接分子，形成二维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98ad/2968994/69354c444eae/e-65-0o864-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98ad/2968994/13699d97d48f/e-65-0o864-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98ad/2968994/006c64cd873e/e-65-0o864-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98ad/2968994/0ff642aceae0/e-65-0o864-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98ad/2968994/69354c444eae/e-65-0o864-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98ad/2968994/13699d97d48f/e-65-0o864-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98ad/2968994/006c64cd873e/e-65-0o864-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98ad/2968994/0ff642aceae0/e-65-0o864-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98ad/2968994/69354c444eae/e-65-0o864-fig4.jpg

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