Huang Hai-Tao
Pharmacy School, Qiqihar Medical University, Qiqihar 161006, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 28;65(Pt 4):o892. doi: 10.1107/S160053680900960X.
The title compound, C(20)H(19)N(3)O(2), was obtained by the condensation of 4-(dimethyl-amino)benzaldehyde with 3-hydr-oxy-2-naphthohydrazide. The mol-ecule is approximately planar, with an intra-molecular N-H⋯O hydrogen bond involving the imino H atom and the hydr-oxy O atom. The dihedral angle between the benzene ring and the naphthyl mean plane is 2.72 (13)°. In the crystal structure, symmetry-related mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds, forming chains propagating in the c-axis direction.
标题化合物C(20)H(19)N(3)O(2)是由4-(二甲基氨基)苯甲醛与3-羟基-2-萘酰肼缩合得到的。分子近似平面结构,存在一个分子内N-H⋯O氢键,涉及亚氨基H原子和羟基O原子。苯环与萘基平均平面之间的二面角为2.72 (13)°。在晶体结构中,对称相关的分子通过分子间O-H⋯O氢键相连,形成沿c轴方向延伸的链。