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二-μ-羟基-双-[溴化二对甲苯基锡(IV)]

Di-μ-hydroxido-bis-[bromidodi-p-tolyl-tin(IV)].

作者信息

Lo Kong Mun, Ng Seik Weng

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):m716. doi: 10.1107/S1600536809019758.

DOI:10.1107/S1600536809019758
PMID:21582660
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969444/
Abstract

The Sn atoms in the dinuclear title compound, [Sn(2)Br(2)(C(7)H(7))(4)(OH)(2)], exist in distorted trigonal-bipyramidal BrSnC(2)O(2) coordination geometries. Each of the two independent dinuclear mol-ecules comprising the asymmetric unit is disposed about a center of inversion. In the crystal, molecules are linked by an O-H⋯ hydrogen bond.

摘要

在双核标题化合物[Sn₂Br₂(C₇H₇)₄(OH)₂]中,Sn原子以扭曲的三角双锥BrSnC₂O₂配位几何构型存在。构成不对称单元的两个独立双核分子中的每一个都围绕一个反演中心排列。在晶体中,分子通过O—H⋯氢键相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/293f/2969444/1d3cfee78a6e/e-65-0m716-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/293f/2969444/76c865e5cb2c/e-65-0m716-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/293f/2969444/1d3cfee78a6e/e-65-0m716-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/293f/2969444/76c865e5cb2c/e-65-0m716-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/293f/2969444/1d3cfee78a6e/e-65-0m716-fig2.jpg

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