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链状聚[[(乙醇-κO)钠(I)]-二-μ-水合-[(外消旋-2'-羟基-1,1'-联萘-2-基磷酸根-κO)钠]-三-μ-水合]

catena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2'-hydr-oxy-1,1'-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua].

作者信息

Tachibana Yuya, Maeda Yasukatsu

机构信息

Industrial Technology Center of Wakayama Prefecture, 60 Ogura, Wakayama 649-6261, Japan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 10;65(Pt 7):m753. doi: 10.1107/S1600536809021394.

DOI:10.1107/S1600536809021394
PMID:21582689
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969360/
Abstract

The asymmetric unit of the polymeric title compound, Na(2)(C(20)H(13)O(5)P)(C(2)H(6)O)(H(2)O)(5), consists of two Na(I) ions, one 2'-hydr-oxy-1,1'-binaphthyl-2-yl phosphate anion, one ethanol ligand and five water molecules of crysallization. Each Na(I) ion has a distorted octa-hedral coordination geometry. The phosphate anion coordinates to one Na(I) ion and the ethanol mol-ecule coordinates to the other. The five water mol-ecules bridge the Na(I) ions, forming an inorganic chain structure along the b axis. The chains are connected by O-H⋯O hydrogen bonds into an organic-inorganic hybrid layer parallel to (001).

摘要

聚合标题化合物[Na₂(C₂₀H₁₃O₅P)(C₂H₆O)(H₂O)₅]ₙ的不对称单元由两个Na(I)离子、一个2'-羟基-1,1'-联萘-2-基磷酸根阴离子、一个乙醇配体和五个结晶水分子组成。每个Na(I)离子具有扭曲的八面体配位几何构型。磷酸根阴离子与一个Na(I)离子配位，乙醇分子与另一个Na(I)离子配位。五个水分子桥连Na(I)离子，沿b轴形成无机链结构。这些链通过O-H⋯O氢键连接成平行于(001)的有机-无机杂化层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd5/2969360/f28b731c9a1f/e-65-0m753-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd5/2969360/247e69e22cd3/e-65-0m753-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd5/2969360/a82442eeb931/e-65-0m753-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd5/2969360/f28b731c9a1f/e-65-0m753-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd5/2969360/247e69e22cd3/e-65-0m753-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd5/2969360/a82442eeb931/e-65-0m753-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd5/2969360/f28b731c9a1f/e-65-0m753-fig3.jpg

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本文引用的文献

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