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双[(1S*,2S*)-反式-1,2-双-(二苯基膦酰氧基)环己烷]氯钌(II)三氟甲磺酸酯二氯甲烷溶剂化物

Bis[(1S*,2S*)-trans-1,2-bis-(diphenyl-phosphin-oxy)cyclo-hexa-ne]chlorido-ruthenium(II) trifluoro-methane-sulfonate dichloro-methane disolvate.

作者信息

Clark George R, Lensink Cornelis, Slade Angela T, Wright L James

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m804-5. doi: 10.1107/S1600536809023034.

DOI:10.1107/S1600536809023034
PMID:21582729
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969446/
Abstract

The crystal structure of a racemic mixture of the title ruthenium(II) complex, [RuCl(C(30)H(30)O(2)P(2))(2)]CF(3)SO(3)·2CH(2)Cl(2), reveals that the coordination geometry about the coordinatively unsaturated metal centre is approximately trigonal-pyramidal, with the chlorine atom occupying one of the equatorial positions. The axial Ru-P bonds are longer than the equatorial Ru-P bonds and there is an acute P-Ru-P angle.

摘要

标题钌（II）配合物[RuCl(C₃₀H₃₀O₂P₂)₂]CF₃SO₃·2CH₂Cl₂的外消旋混合物的晶体结构表明，关于配位不饱和金属中心的配位几何形状近似为三角锥型，氯原子占据一个赤道位置。轴向的Ru-P键比赤道面的Ru-P键长，且存在一个锐角的P-Ru-P角。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5215/2969446/6b04352d9799/e-65-0m804-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5215/2969446/771a2a290d98/e-65-0m804-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5215/2969446/6b04352d9799/e-65-0m804-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5215/2969446/771a2a290d98/e-65-0m804-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5215/2969446/6b04352d9799/e-65-0m804-fig2.jpg

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