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N-羟基-N-[(1S*,2R*)-2-(1-萘基)环戊-3-烯-1-基]叔丁基氨基甲酸酯

tert-Butyl N-hydr-oxy-N-[(1S*,2R*)-2-(1-naphth-yl)cyclo-pent-3-en-1-yl]carbamate.

作者信息

Lough Alan J, Machin Ben P, Tam William

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):o1481. doi: 10.1107/S1600536809020315.

DOI:10.1107/S1600536809020315
PMID:21582783
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969270/
Abstract

The relative stereochemistry of the title compound, C(20)H(23)NO(3), was established by X-ray analysis. The asymmetric unit contains two independent mol-ecules. In the crystal structure, each type of mol-ecule forms a centrosymmetric dimer via pairs of inter-molecular O-H⋯O hydrogen bonds, resulting in an R(2) (2)(10) loop in each case.

摘要

标题化合物C(20)H(23)NO(3)的相对立体化学通过X射线分析得以确定。不对称单元包含两个独立分子。在晶体结构中，每种类型的分子通过分子间O-H⋯O氢键对形成中心对称二聚体，每种情况下均产生一个R(2) (2)(10)环。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5001/2969270/7eae5c653c83/e-65-o1481-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5001/2969270/c66a705d85c5/e-65-o1481-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5001/2969270/66916f396d48/e-65-o1481-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5001/2969270/b05643fc7373/e-65-o1481-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5001/2969270/7eae5c653c83/e-65-o1481-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5001/2969270/c66a705d85c5/e-65-o1481-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5001/2969270/66916f396d48/e-65-o1481-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5001/2969270/b05643fc7373/e-65-o1481-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5001/2969270/7eae5c653c83/e-65-o1481-fig4.jpg

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