2-（5-溴-3-甲基亚磺酰基-1-苯并呋喃-2-基）乙酸异戊酯
Isoamyl 2-(5-bromo-3-methyl-sulfin-yl-1-benzofuran-2--yl)acetate.
作者信息
Choi Hong Dae, Seo Pil Ja, Son Byeng Wha, Lee Uk
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):o1498. doi: 10.1107/S1600536809020613.
Abstract
In the title compound, C(16)H(19)BrO(4)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The crystal structure exhibits aromatic π-π inter-actions between the benzene rings of adjacent mol-ecules [centroid-centroid distance = 3.643 (2) Å] and nonclassical C-H⋯O hydrogen bonds.
摘要
在标题化合物C₁₆H₁₉BrO₄S中，亚甲基磺酰基取代基的O原子和甲基位于苯并呋喃片段平面的相对两侧。晶体结构显示相邻分子的苯环之间存在芳香π-π相互作用[质心-质心距离 = 3.643 (2) Å]以及非经典的C-H⋯O氢键。
相似文献
1
Isoamyl 2-(5-bromo-3-methyl-sulfin-yl-1-benzofuran-2--yl)acetate.2-（5-溴-3-甲基亚磺酰基-1-苯并呋喃-2-基）乙酸异戊酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):o1498. doi: 10.1107/S1600536809020613.
2
Propyl 2-(5-bromo-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.2-(5-溴-3-甲基亚磺酰基-1-苯并呋喃-2-基)乙酸丙酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 13;65(Pt 3):o520. doi: 10.1107/S160053680900453X.
3
Methyl 2-(5-iodo-7-methyl-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.2-(5-碘-7-甲基-3-甲基亚磺酰基-1-苯并呋喃-2-基)乙酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2009 May 14;65(Pt 6):o1240. doi: 10.1107/S1600536809016298.
4
Methyl 2-(5-chloro-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.2-（5-氯-3-甲基亚磺酰基-1-苯并呋喃-2-基）乙酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 18;64(Pt 11):o2139. doi: 10.1107/S1600536808033503.
5
Propyl 2-(5-chloro-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.2-(5-氯-3-甲基亚磺酰基-1-苯并呋喃-2-基)乙酸丙酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 13;65(Pt 3):o521. doi: 10.1107/S1600536809004735.
6
Ethyl 2-(5-fluoro-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.2-（5-氟-3-甲基亚磺酰基-1-苯并呋喃-2-基）乙酸乙酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):o1826. doi: 10.1107/S1600536809025938.
7
2-Chloro-ethyl 2-(5-bromo-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.2-氯乙基 2-(5-溴-3-甲基亚磺酰基-1-苯并呋喃-2-基)乙酸酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 10;65(Pt 5):o1025. doi: 10.1107/S1600536809012847.
8
Butyl 2-(5-bromo-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.2-（5-溴-3-甲基亚磺酰基-1-苯并呋喃-2-基）乙酸丁酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):o265. doi: 10.1107/S1600536808043985.
9
2-(4-Bromo-phen-yl)-5-fluoro-3-methyl-sulfinyl-1-benzofuran.2-（4-溴苯基）-5-氟-3-甲亚磺酰基-1-苯并呋喃
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 8;65(Pt 9):o2084. doi: 10.1107/S1600536809030190.
10
2-(4-Bromo-phen-yl)-5,6-methyl-enedi-oxy-3-phenyl-sulfinyl-1-benzofuran benzene solvate.
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 19;65(Pt 10):o2503. doi: 10.1107/S1600536809037283.
本文引用的文献
1
Propyl 2-(5-bromo-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.2-(5-溴-3-甲基亚磺酰基-1-苯并呋喃-2-基)乙酸丙酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 13;65(Pt 3):o520. doi: 10.1107/S160053680900453X.
2
Butyl 2-(5-bromo-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.2-（5-溴-3-甲基亚磺酰基-1-苯并呋喃-2-基）乙酸丁酯
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):o265. doi: 10.1107/S1600536808043985.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
4
Inhibition of fibril formation in beta-amyloid peptide by a novel series of benzofurans.新型苯并呋喃系列对β-淀粉样肽原纤维形成的抑制作用。
Biochem J. 1999 May 15;340 ( Pt 1)(Pt 1):283-9.
Zotero 插件