Lv Lu-Ping, Yu Wen-Bo, Li Wei-Wei, Zhang Yong-Zhao, Hu Xian-Chao
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 10;65(Pt 7):o1548. doi: 10.1107/S1600536809021631.
The title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N double bond. The non-H atoms of the mol-ecule are essentially coplanar, with a maximum deviation of 0.015 (2) Å. An intra-molecular O-H⋯N inter-action is observed. In the crystal structure, the mol-ecules are linked into a two-dimensional network parallel to the ac plane by N-H⋯O hydrogen bonds involving the meth-oxy O atom and by two C-H⋯O hydrogen bonds involving the carbonyl O atom. In addition, an intermolecular C-H⋯π inter-action is observed.
标题化合物C(10)H(12)N(2)O(4)相对于C=N双键采取反式构型。分子中的非H原子基本共面,最大偏差为0.015 (2) Å。观察到分子内O-H⋯N相互作用。在晶体结构中,分子通过涉及甲氧基O原子的N-H⋯O氢键和涉及羰基O原子的两个C-H⋯O氢键连接成平行于ac平面的二维网络。此外,还观察到分子间C-H⋯π相互作用。