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N-亚苄基去氢枞胺

N-Benzyl-idenenordehydro-abietylamine.

作者信息

Rao Xiao-Ping, Wu Yong, Song Zhan-Qian, Shang Shi-Bin

机构信息

Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):o1639. doi: 10.1107/S1600536809022909.

DOI:10.1107/S1600536809022909
PMID:21582903
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969393/
Abstract

THE TITLE COMPOUND [SYSTEMATIC NAME: (1R,4aS,10aR,E)-N-benzyl-idene-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa-hydro-phenanthren-1-amine], C(26)H(33)N, has been synthesized from nor-dehydro-abietylamine and benzaldehyde. The two cyclo-hexane rings form a trans ring junction with classic chair and half-chair conformations, respectively, the two methyl groups are on the same side of tricyclic hydro-phenanthrene structure. The dihedral angle between two benzene rings is 44.2 (4)°. The C=N bond is in an E configuration.

摘要

标题化合物[系统名称：(1R,4aS,10aR,E)-N-亚苄基-7-异丙基-1,4a-二甲基-1,2,3,4,4a,9,10,10a-八氢菲-1-胺]，C(26)H(33)N，由去氢枞胺和苯甲醛合成。两个环己烷环分别以经典的椅式和半椅式构象形成反式环连接，两个甲基位于三环氢化菲结构的同一侧。两个苯环之间的二面角为44.2 (4)°。C=N键呈E构型。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8ac/2969393/1fd596c37a8a/e-65-o1639-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8ac/2969393/1fd596c37a8a/e-65-o1639-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8ac/2969393/1fd596c37a8a/e-65-o1639-fig1.jpg

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本文引用的文献

1
Synthesis, structure analysis and cytotoxicity studies of novel unsymmetrically n,n'-substituted ureas from dehydroabietic Acid.来自脱氢枞酸的新型不对称N，N'-取代脲的合成、结构分析及细胞毒性研究
Chem Pharm Bull (Tokyo). 2008 Nov;56(11):1575-8. doi: 10.1248/cpb.56.1575.
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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.