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2,2'-[(E,E)-1,1'-(2,2-二甲基丙烷-1,3-二亚基二腈基)二亚乙基]二苯酚

2,2'-[(E,E)-1,1'-(2,2-Dimethyl-propane-1,3-diyldinitrilo)diethyl-idyne]diphenol.

作者信息

Montazerozohori Morteza, Habibi Mohammad Hossein, Hojjati Ahmad, Mokhtari Reza, Yamane Yuki, Suzuki Takayoshi

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):o1662-3. doi: 10.1107/S1600536809022855.

DOI:10.1107/S1600536809022855
PMID:21582924
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969254/
Abstract

The title Schiff base, C(21)H(26)N(2)O(2), contains two intra-molecular O-H⋯N hydrogen bonds between the hydroxyl groups and the nearest imine N atoms, each leading to a six-membered ring. Weak C-H⋯O hydrogen bonds result in a ladder network running along the a axis. In addition, inter-molecular C-H⋯π inter-actions serve to stabilize the extended structure.

摘要

席夫碱C(21)H(26)N(2)O(2)的结构中，羟基与最近的亚胺氮原子之间存在两个分子内O-H⋯N氢键，每个氢键都形成一个六元环。弱C-H⋯O氢键形成了沿a轴延伸的梯状网络。此外，分子间的C-H⋯π相互作用有助于稳定这种扩展结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8655/2969254/535c82fb9ce2/e-65-o1662-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8655/2969254/8657cd7fc63a/e-65-o1662-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8655/2969254/e9c98d7281b8/e-65-o1662-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8655/2969254/535c82fb9ce2/e-65-o1662-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8655/2969254/8657cd7fc63a/e-65-o1662-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8655/2969254/e9c98d7281b8/e-65-o1662-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8655/2969254/535c82fb9ce2/e-65-o1662-fig3.jpg

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