Yan Juan, Liu Guang-Xiang
Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246003, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 May 14;65(Pt 6):m641. doi: 10.1107/S1600536809017073.
The Cd atom in the title compound, Cd(C(12)H(10)N(2)O)(3)(2), adopts a distorted octa-hedral geometry, being ligated by six N atoms from three different phenyl-2-pyridyl ketone oxime ligands. In the crystal structure, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into a chain structure propagating along [100]. The chains are further linked into a three-dimensional supra-molecular structure via van der Waals forces.
在标题化合物Cd(C₁₂H₁₀N₂O)₃₂中，镉原子采用扭曲的八面体几何构型，由来自三个不同的苯基-2-吡啶基酮肟配体的六个氮原子配位。在晶体结构中，分子间的O—H⋯O和C—H⋯O氢键将分子连接成沿[100]方向延伸的链状结构。这些链通过范德华力进一步连接成三维超分子结构。
