二氯双（吡啶-2-羧基-κN,O）铂（IV）乙腈溶剂化物
Dichloridobis(pyridine-2-carboxyl-ato-κN,O)platinum(IV) acetonitrile solvate.
作者信息
Kim Nam-Ho, Hwang In-Chul, Ha Kwang
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 May 20;65(Pt 6):m667. doi: 10.1107/S1600536809017966.
The asymmetric unit of the title compound, [PtCl(2)(C(6)H(4)NO(2))(2)]·CH(3)CN, contains a neutral Pt(IV) complex and an acetonitrile solvent mol-ecule. In the complex, the Pt(4+) atom is six-coordinated in a distorted octa-hedral environment by two N atoms and two O atoms from two pyridine-carboxyl-ate (pic) ligands and two Cl atoms. The Cl atoms are cis with respect to each other. The compound displays inter- and intra-molecular C-H⋯O and C-H⋯Cl hydrogen bonding.
标题化合物[PtCl₂(C₆H₄NO₂)₂]·CH₃CN的不对称单元包含一个中性的Pt(IV)配合物和一个乙腈溶剂分子。在该配合物中，Pt⁴⁺原子由来自两个吡啶羧酸酯（吡啶甲酸酯，pic）配体的两个N原子和两个O原子以及两个Cl原子在扭曲的八面体环境中进行六配位。两个Cl原子彼此呈顺式。该化合物表现出分子间和分子内的C—H⋯O和C—H⋯Cl氢键。
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