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双[μ-2-(2-羧基苯基亚苯基)乙酸根]-κO,O:O;κO:O,O-双-[水合-(1,10-菲咯啉-κN,N')镍(II)]

Bis[μ-2-(2-carboxyl-atophen-yl)acetato]-κO,O:O;κO:O,O-bis-[aqua-(1,10-phenanthroline-κN,N')nickel(II)].

作者信息

Li Feng, Zeng Huifang, Yan Zhaowei, Li Taohai

机构信息

College of Chemistry, Key Laboratory of Environmentally Friendly Chemistry and Applications of the Ministry of Education, Xiangtan University, Hunan 411105, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 May 23;65(Pt 6):m681. doi: 10.1107/S1600536809018339.

DOI:10.1107/S1600536809018339
PMID:21583040
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969824/
Abstract

The title compound, [Ni(2)(C(9)H(6)O(4))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], is isostructural with the Zn(II) analogue. Each Ni(II) atom is coordinated in a distorted octa-hedral geometry by three O atoms from two homophthalate anions, one aqua O atom and two 1,10-phenanthroline N atoms. The two Ni(II) atoms are linked by two bridging homophthalate dianions into a centrosymmetric dinuclear unit. The dinuclear units are linked into one-dimensional ladder-like chains along [100] by O-H⋯O hydrogen bonds between the coordinated water mol-ecules and one of the O atoms of the carboxyl-atomethyl group.

摘要

标题化合物[Ni₂(C₉H₆O₄)₂(C₁₂H₈N₂)₂(H₂O)₂]与锌(II)类似物同构。每个Ni(II)原子由来自两个均苯二甲酸根阴离子的三个O原子、一个水合O原子和两个1,10 - 菲咯啉N原子以扭曲的八面体几何构型配位。两个Ni(II)原子通过两个桥连的均苯二甲酸二阴离子连接成一个中心对称的双核单元。双核单元通过配位水分子与羧基 - 甲基基团的一个O原子之间的O - H⋯O氢键沿[100]方向连接成一维梯状链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9939/2969824/a187292d2658/e-65-0m681-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9939/2969824/ae93d184de71/e-65-0m681-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9939/2969824/a187292d2658/e-65-0m681-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9939/2969824/ae93d184de71/e-65-0m681-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9939/2969824/a187292d2658/e-65-0m681-fig2.jpg

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