5-二茂铁基-5a-羟基-1-甲基-10-氧代-2,3,3a,4,5a,10-六氢-1H-茚并[1,2:2',3']呋喃并[3',4'-b]吡咯-3a-羧酸甲酯
Methyl 5-ferrocenyl-5a-hydr-oxy-1-methyl-10-oxo-2,3,3a,4,5a,10-hexa-hydro-1H-indeno[1,2:2',3']furo[3',4'-b]pyrrole-3a-carboxyl-ate.
作者信息
Kamala E Theboral Sugi, Nirmala S, Sudha L, Kathiravan S, Raghunathan R
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 May 29;65(Pt 6):m687-8. doi: 10.1107/S1600536809018583.
Abstract
In the title compound, [Fe(C(5)H(5))(C(21)H(20)NO(5))], the pyrrolidine and cyclo-penta-none rings exhibit a twist conformation. The pyrrolidine ring is almost perpendicular to the cyclo-penta-none ring, making a dihedral angle of 81.91 (6)°. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond and C-H⋯O inter-actions. The crystal structure is stabilized by inter-molecular C-H⋯O inter-actions.
摘要
在标题化合物[Fe(C₅H₅)(C₂₁H₂₀NO₅)]中，吡咯烷环和环戊酮环呈扭曲构象。吡咯烷环几乎垂直于环戊酮环，二面角为81.91 (6)°。分子构象通过分子内O—H⋯N氢键和C—H⋯O相互作用得以稳定。晶体结构通过分子间C—H⋯O相互作用得以稳定。
Zotero 插件