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(1-羟基-1,2-二苯基乙基)膦酸二乙酯

Diethyl (1-hydr-oxy-1,2-diphenyl-ethyl)phospho-nate.

作者信息

Acar Nurcan, Tahir M Nawaz, Tariq Riaz H, Yilmaz Hamza

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):o1203. doi: 10.1107/S160053680901602X.

Abstract

In the title compound, C(18)H(23)O(4)P, the dihedral angle between the aromatic ring planes is 69.94 (14)°. Both ethyl side chains are disordered over two sets of sites, with occupancy ratios of 80:20 and 70:30. In the crystal, inversion dimers linked by pairs of O-H⋯O hydrogen bonds occur, leading to R(2) (1)(8) loops, and C-H⋯O and weak C-H⋯π inter-actions are also seen.

摘要

在标题化合物C₁₈H₂₃O₄P中,芳香环平面之间的二面角为69.94 (14)°。两个乙基侧链在两组位置上无序分布,占有率分别为80:20和70:30。在晶体中,通过O—H⋯O氢键对连接形成了反演二聚体,产生了R₂²(₈)环,同时也存在C—H⋯O和弱C—H⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2bf2/2969590/65c118f2c556/e-65-o1203-fig1.jpg

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