Li Jiang-Sheng, Li Xun
School of Chemistry and Biological Engineering, Changsha University of Science & Technology, Changsha 410004, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):o1228. doi: 10.1107/S1600536809015670.
In the title compound, C(11)H(11)N(2)O(2)S(+)·NO(3) (-), the dihedral angle between the benzene and pyridinium rings is 87.59 (8)°. An intra-molecular C-H⋯O inter-action occurs in the cation. In the crystal structure, ion pairs occur, being linked by two strong N-H⋯O inter-actions, forming R(2) (2)(8) loops. The packing is further stabilized by weak C-H⋯O inter-actions.
在标题化合物C(11)H(11)N(2)O(2)S(+)·NO(3) (-)中,苯环与吡啶鎓环之间的二面角为87.59 (8)°。阳离子中存在分子内C-H⋯O相互作用。在晶体结构中,通过两个强N-H⋯O相互作用形成离子对,形成R(2) (2)(8)环。通过弱C-H⋯O相互作用进一步稳定了堆积结构。