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链状聚[[二水合镍（II）]-双-（μ-4-吡啶亚磺酸盐）-κN，O；κO，N]

catena-Poly[[diaqua-nickel(II)]-bis-(μ-pyridine-4-sulfinato)-κN,O;κO,N].

作者信息

Du Zhong-Xiang, Ji Su-Ning

机构信息

Department of Chemistry, Luoyang Normal University, Luoyang, Henan 471022, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 1;65(Pt 8):m846. doi: 10.1107/S1600536809024258.

DOI:10.1107/S1600536809024258
PMID:21583316
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977425/
Abstract

In the title coordination polymer, Ni(C(5)H(4)NO(2)S)(2)(H(2)O)(2), the Ni(II) ion is located on an inversion centre and is octa-hedrally coordinated by two N and two O atoms of four symmetry-related and deprotonated pyridine-4-sulfinate (ps) ligands together with two water mol-ecules in axial positions. The ps(-) anions, acting as μ(2)-bridging ligands, link neighbouring Ni(II) ions into a chain structure along the c axis. These polymeric chains are extended into a three-dimensional framework via inter-molecular O-H⋯O hydrogen bonds with participation of the water mol-ecules.

摘要

在标题配位聚合物[Ni(C₅H₄NO₂S)₂(H₂O)₂]ₙ中，Ni(II)离子位于一个对称中心上，由四个对称相关且去质子化的吡啶-4-亚磺酸盐（ps）配体的两个N原子和两个O原子以及轴向位置的两个水分子八面体配位。ps⁻阴离子作为μ₂-桥联配体，将相邻的Ni(II)离子沿c轴连接成链状结构。这些聚合物链通过水分子参与的分子间O—H⋯O氢键扩展成三维框架。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c240/2977425/0c46cf826609/e-65-0m846-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c240/2977425/914b5d561ac6/e-65-0m846-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c240/2977425/1b9b93516304/e-65-0m846-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c240/2977425/0c46cf826609/e-65-0m846-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c240/2977425/914b5d561ac6/e-65-0m846-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c240/2977425/1b9b93516304/e-65-0m846-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c240/2977425/0c46cf826609/e-65-0m846-fig3.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.