{双[2-(二苯基膦基)苯基]醚-κP:P'}(2,2'-联苯-4,4'-二甲酸二甲酯-κN:N')铜(I)六氟磷酸酯乙腈溶剂化物
{Bis[2-(diphenyl-phosphino)phen-yl] ether-κP:P'}(dimethyl 2,2'-biphenyl-4,4'-dicarboxyl-ate-κN:N')copper(I) hexa-fluorido-phosphate acetonitrile solvate.
作者信息
Yu Ai-Guo, Zhang Ming, Yang Guang-Di, Ye Ling, Ma Yu-Guang
机构信息
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 4;65(Pt 8):m875. doi: 10.1107/S1600536809024982.
In the title compound, [Cu(C(14)H(12)N(2)O(4))(C(36)H(28)OP(2))]PF(6)·CH(3)CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2'-biphenyl-4,4'-dicarboxyl-ate ligand and two P atoms from the bis-[2-(diphenyl-phosphino)phen-yl] ether ligand in a distorted tetra-hedral environment. In the cation, the short distance of 3.870 (4) Å between the centroids of the benzene and phenyl rings suggests the existence of intra-molecular π-π inter-actions.
在标题化合物[Cu(C₁₄H₁₂N₂O₄)(C₃₆H₂₈OP₂)]PF₆·CH₃CN中，Cu(I)离子在扭曲的四面体环境中由来自2,2'-联苯-4,4'-二甲酸二甲酯配体的两个N原子和来自双-[2-(二苯基膦基)苯基]醚配体的两个P原子配位。在阳离子中，苯环和苯基环质心之间3.870 (4) Å的短距离表明存在分子内π-π相互作用。
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