Shi Li-Ping, Tiekink Edward R T
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 8;65(Pt 8):m885-6. doi: 10.1107/S1600536809024246.
In the polymeric title compound, Cd(C(4)H(2)O(4))(C(19)H(12)N(4)O)(2), the Cd(II) centre is eight-coordinated within an N(4)O(4) donor set derived from two chelating 4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol ligands and two asymmetrically chelating carboxyl-ate residues of bridging fumarate dianions. The linear chains are linked into a layer in the ac plane via O-H⋯O(carboxyl-ate) hydrogen bonds. Layers are connected into double layers via N-H⋯O(carboxyl-ate) hydrogen bonds and these stack along the b axis. C-H⋯π inter-actions are also present. Disorder in the ethyl-ene portion of the fumarate was modelled over two positions, the major component having a site-occupancy factor of 0.677 (15).
在聚合标题化合物[Cd(C₄H₂O₄)(C₁₉H₁₂N₄O)₂]ₙ中，Cd(II)中心在一个由两个螯合的4-(1H-咪唑并[4,5-f][1,10]菲咯啉-2-基)苯酚配体以及桥连富马酸二阴离子的两个不对称螯合羧酸根残基所衍生的N₄O₄供体集合内呈八配位。线性链通过O—H⋯O(羧酸根)氢键在ac平面内连接成层。层通过N—H⋯O(羧酸根)氢键连接成双层，且这些双层沿b轴堆叠。还存在C—H⋯π相互作用。富马酸酯的乙烯部分的无序性在两个位置上进行了建模，主要组分的占有率为0.677 (15)。
