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反式-二水合双[5-羧基-2-(3-吡啶基)-1H-咪唑-4-羧酸根合-κN,O]铁(II)

trans-Diaqua-bis[5-carb-oxy-2-(3-pyrid-yl)-1H-imidazole-4-carboxyl-ato-κN,O]iron(II).

作者信息

Liu Wei, Zhang Gang, Li Xia, Wu Ben-Lai, Zhang Hong-Yun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):m938-9. doi: 10.1107/S1600536809027457.

DOI:10.1107/S1600536809027457
PMID:21583390
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977312/
Abstract

In the title complex, [Fe(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Fe(II) atom is located on an inversion centre and is trans-coordinated by two N,O-bidentate 5-carb-oxy-2-(3-pyrid-yl)-1H-imidazole-4-carb-oxy-l-ate ligands and two water mol-ecules, defining a distorted octa-hedral environment. A two-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds extending parallel to (110) helps to stabilize the crystal packing.

摘要

在标题配合物[Fe(C₁₀H₆N₃O₄)₂(H₂O)₂]中，Fe(II)原子位于一个对称中心上，由两个N,O-双齿的5-羧基-2-(3-吡啶基)-1H-咪唑-4-羧基阴离子配体和两个水分子反式配位，形成一个扭曲的八面体环境。一个平行于(110)延伸的由N-H⋯O和O-H⋯O氢键构成的二维网络有助于稳定晶体堆积。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f000/2977312/fdfcc144ac05/e-65-0m938-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f000/2977312/c36e967487de/e-65-0m938-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f000/2977312/0278f44c9fee/e-65-0m938-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f000/2977312/fdfcc144ac05/e-65-0m938-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f000/2977312/c36e967487de/e-65-0m938-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f000/2977312/0278f44c9fee/e-65-0m938-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f000/2977312/fdfcc144ac05/e-65-0m938-fig3.jpg

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