1,4-重氮双环-[2.2.2]辛烷四溴化镉（II）一水合物
1,4-Diazo-niabicyclo-[2.2.2]octane tetra-bromidocadmate(II) monohydrate.
作者信息
Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):m973. doi: 10.1107/S160053680902813X.
Abstract
The metal atom in the anion of the title salt, (C(6)H(14)N(2))[CdBr(4)]·H(2)O, shows a slightly distorted tetra-hedral coordination. The water mol-ecule is involved in three hydrogen bonds, viz. one N-H⋯O and two O-H⋯Br, and an N-H⋯Br inter-action consolidates the three-dimensional network.
摘要
标题盐（C₆H₁₄N₂）[CdBr₄]·H₂O的阴离子中的金属原子呈现出略微扭曲的四面体配位。水分子参与形成了三个氢键，即一个N-H⋯O氢键和两个O-H⋯Br氢键，并且一个N-H⋯Br相互作用巩固了三维网络结构。
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