（乙酰丙酮根-κO,O'）水合-[2-（2-硝基苯氧基）-N'-（2-氧化苯基亚苄基-κO）乙酰肼基-κO,N']锰（III）
(Acetyl-acetonato-κO,O')aqua-[2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidato-κO,N']manganese(III).
作者信息
Xiao Zi-Jing
机构信息
College of Materials Science & Engineering, Huaqiao University, Quanzhou 362021, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 25;65(Pt 8):m986. doi: 10.1107/S1600536809028177.
In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octa-hedral coordination geometry. It is coordinated by a phen-oxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidate dianion, by two O atoms of the acetyl-acetonate anion and by the O atom of a coordinated water mol-ecule. In the crystal structure, complex mol-ecules are linked into centrosymmetric dimeric units through four inter-molecular O-H⋯O hydrogen bonds involving both H atoms of the coordinated water mol-ecule.
在标题配合物[Mn(C₁₅H₁₁N₃O₅)(C₅H₇O₂)(H₂O)]中，Mn(III)离子具有扭曲的八面体配位几何构型。它由2-(2-硝基苯氧基)-N'-(2-氧化苯亚甲基-κO)乙酰肼二价阴离子的一个苯氧基O原子、一个肼基N原子和一个羰基O原子、乙酰丙酮阴离子的两个O原子以及一个配位水分子的O原子配位。在晶体结构中，配合物分子通过涉及配位水分子两个H原子的四个分子间O-H⋯O氢键连接成中心对称的二聚体单元。
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