水合 -（1,10 - 菲咯啉 - κN,N'）双 -（三甲基乙酸根）- κO,O';κO - 钴（II）
Aqua-(1,10-phenanthroline-κN,N')bis-(trimethyl-acetato)-κO,O';κO-cobalt(II).
作者信息
Chen Xiao-Dan, Chen Hong-Xian, Li Zhong-Shu, Zhang Huai-Hong, Sun Bai-Wang
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 29;65(Pt 8):m997. doi: 10.1107/S1600536809027251.
In the title compound, [Co(C(5)H(9)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Co(II) atom is coordinated in a distorted octahedral environment by three carboxyl O atoms of two trimethyl-acetate ligands, one aqua O atom and two N atoms from 1,10-phen-anthroline. The crystal structure is stabilized by O-H⋯O hydrogen bonds and π-π stacking inter-actions [inter-planar distance between inter-digitating 1,10-phenanthroline ligands = 3.378 (2) Å].
在标题化合物[Co(C₅H₉O₂)₂(C₁₂H₈N₂)(H₂O)]中，Co(II)原子在一个扭曲的八面体环境中，由两个三甲基乙酸酯配体的三个羧基O原子、一个水分子O原子以及来自1,10 - 菲咯啉的两个N原子配位。晶体结构通过O—H⋯O氢键和π - π堆积相互作用得以稳定[相互交错的1,10 - 菲咯啉配体之间的平面间距 = 3.378(2) Å]。
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