Nirmala S, Kamala E Theboral Sugi, Sudha L, Kathiravan S, Raghunathan R
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):o1938. doi: 10.1107/S1600536809027639.
In the title compound, C(27)H(27)NO(4), both the pyrrolidine rings in the pyrrolizine ring system adopt envelope conformations, whereas the dihydro-pyran ring adopts a half-chair conformation. The methoxy-phenyl group is oriented at an angle of 53.72 (4)° with respect to the naphthalene ring system. Intra-molecular C-H⋯O hydrogen bonds are observed. The crystal structure is stabilized by weak inter-molecular C-H⋯π inter-actions.
在标题化合物C(27)H(27)NO(4)中,吡咯嗪环系中的两个吡咯烷环均呈信封式构象,而二氢吡喃环呈半椅式构象。甲氧基苯基相对于萘环系的取向角度为53.72 (4)°。观察到分子内C—H⋯O氢键。晶体结构通过弱的分子间C—H⋯π相互作用得以稳定。