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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
The Cambridge Structural Database: a quarter of a million crystal structures and rising.剑桥结构数据库:拥有二十五万个晶体结构且数量不断增加。
Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):380-8. doi: 10.1107/s0108768102003890. Epub 2002 May 29.

4,4'-二叔丁基-2,2'-联吡啶

4,4'-Di-tert-butyl-2,2'-bipyridine.

作者信息

Amarante Tatiana R, Figueiredo Sónia, Lopes André D, Gonçalves Isabel S, Almeida Paz Filipe A

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 31;65(Pt 8):o2047. doi: 10.1107/S1600536809029109.

DOI:10.1107/S1600536809029109
PMID:21583710
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977408/
Abstract

In the title compound, C(18)H(24)N(2), the mol-ecular unit adopts a trans conformation around the central C-C bond [N-C-C-N torsion angle of 179.2 (3)°], with the two aromatic rings almost coplanar [dihedral angle of only 0.70 (4)°]. The crystal packing is driven by co-operative contacts involving weak C-H⋯N and C-H⋯π inter-actions, and also the need to fill effectively the available space.

摘要

在标题化合物C(18)H(24)N(2)中,分子单元围绕中心C-C键呈反式构象 [N-C-C-N扭转角为179.2 (3)°],两个芳环几乎共面 [二面角仅为0.70 (4)°]。晶体堆积由涉及弱C-H⋯N和C-H⋯π相互作用的协同接触以及有效填充可用空间的需求驱动。