Keleşoğlu Zeynep, Büyükgüngör Orhan, Albayrak Ciğdem, Odabaşoğlu Mustafa
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 31;65(Pt 8):o2055. doi: 10.1107/S1600536809029924.
The title compound, C(15)H(15)NO(2), adopts the enol-imine tautomeric form. The dihedral angle between the two benzene rings is 48.1 (1)°. Intra-molecular O-H⋯N and O-H⋯O hydrogen bonds generate S(6) and S(5) ring motifs, respectively. In the crystal, mol-ecules are linked into centrosymmetric R(2) (2)(10) dimers via pairs of O-H⋯O hydrogen bonds and the dimers may interact through very weak by π-π inter-actions [centroid-centroid distance = 4.150 (1) Å]. The ethyl group is disordered over two orientations, with occupancies of 0.587 (11) and 0.413 (11).
标题化合物C(15)H(15)NO(2) 采用烯醇-亚胺互变异构形式。两个苯环之间的二面角为48.1 (1)°。分子内的O-H⋯N和O-H⋯O氢键分别生成S(6)和S(5)环模式。在晶体中,分子通过O-H⋯O氢键对连接成中心对称的R(2) (2)(10)二聚体,并且这些二聚体可能通过非常弱的π-π相互作用相互作用[质心-质心距离 = 4.150 (1) Å]。乙基在两个取向之间无序,占有率分别为0.587 (11) 和0.413 (11)。