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（二乙醚）{1-[2-(1-甲基-1H-咪唑-2-基-κN)-1,1-二苯基-乙基]-(1,2,3,3a,7a-η)-茚基}锂（I）

(Diethyl ether){1-[2-(1-methyl-1H-imidazol-2-yl-κN)-1,1-diphenyl-ethyl]-(1,2,3,3a,7a-η)-inden-yl}lithium(I).

作者信息

Sun Guofeng, Tian Chong, Nie Wanli, Borzov Maxim V

机构信息

The North-West University of Xi'an, College of Chemistry and Material Science, Taibai Bei avenue 229, Xi'an 710069, Shaanxi Province, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 2;65(Pt 5):m478. doi: 10.1107/S1600536809011556.

DOI:10.1107/S1600536809011556
PMID:21583733
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977547/
Abstract

In the title compound, [Li(C(27)H(23)N(2))(C(4)H(10)O)], the Li atom possesses a nearly planar trigonal coordination environment (assuming the cyclo-penta-dienyl ring of the indenyl group occupies one coordination place). The diethyl ether ligand adopts a nearly planar W-type conformation.

摘要

在标题化合物[Li(C₂₇H₂₃N₂)(C₄H₁₀O)]中，锂原子具有近乎平面的三角配位环境（假设茚基的环戊二烯基环占据一个配位位置）。二乙醚配体采取近乎平面的W型构象。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/54da/2977547/bd3b33474550/e-65-0m478-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/54da/2977547/bd3b33474550/e-65-0m478-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/54da/2977547/bd3b33474550/e-65-0m478-fig1.jpg

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