双[2-(氨基甲基)吡啶-κN,N']双(硫氰酸根-κN)铜(II)
Bis[2-(amino-meth-yl)pyridine-κN,N']bis-(thio-cyanato-κN)copper(II).
作者信息
Karan Nirmal Kumar, Chan Kai-Ting, Lee Hon Man
机构信息
National Changhua University of Education, Department of Chemistry, Changhua, Taiwan 50058.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 18;65(Pt 5):m525. doi: 10.1107/S1600536809013427.
In the title complex, [Cu(NCS)(2)(C(6)H(8)N(2))(2)], the Cu(II) atom, lying on an inversion center, adopts a Jahn-Teller distorted octahedral CuN(6) coordination geometry. The two bidentate 2-amino-methyl-pyridine ligands are coordinated in a trans fashion, while the two thio-cyanate ligands are at the axial positions and coordinate to the Cu atom in a bent mode with a C-N-Cu angle of 127.49 (10)°. Inter-molecular N-H⋯N and N-H⋯S hydrogen bonds link the copper complex mol-ecules into an infinite two-dimensional network.
在标题配合物[Cu(NCS)(2)(C(6)H(8)N(2))(2)]中，位于对称中心的Cu(II)原子采用了Jahn-Teller畸变的八面体CuN(6)配位几何构型。两个双齿2-氨基甲基吡啶配体以反式方式配位，而两个硫氰酸根配体处于轴向位置，并以弯曲模式与Cu原子配位，C-N-Cu角为127.49 (10)°。分子间的N-H⋯N和N-H⋯S氢键将铜配合物分子连接成一个无限的二维网络。
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