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链状聚[[二氯锌（II）]-μ-1,4-双-（3-吡啶甲基）哌嗪]

catena-Poly[[dichloridozinc(II)]-μ-1,4-bis-(3-pyridylmeth-yl)piperazine].

作者信息

Hardy Aaron M, Laduca Robert L

机构信息

Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825, USA.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 18;65(Pt 5):m537. doi: 10.1107/S1600536809013877.

DOI:10.1107/S1600536809013877
PMID:21583775
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977589/
Abstract

In the title compound, ZnCl(2)(C(16)H(20)N(4)), tetra-hedrally coordinated divalent Zn atoms are ligated by two Cl atoms and two N-donor atoms from two 1,4-bis-(3-pyridylmeth-yl)-piperazine (3-bpmp) ligands. The tethering 3-bpmp ligands promote the formation of ZnCl(2)(3-bpmp) chains situated parallel to (02). These chains aggregate via C-H⋯Cl inter-actions to form supra-molecular layers, which in turn stack to construct the three-dimensional crystal structure.

摘要

在标题化合物[ZnCl₂(C₁₆H₂₀N₄)]ₙ中，呈四面体配位的二价锌原子由两个氯原子和来自两个1,4-双(3-吡啶甲基)哌嗪(3-bpmp)配体的两个氮供体原子配位。连接性的3-bpmp配体促使形成平行于(02)的[ZnCl₂(3-bpmp)]ₙ链。这些链通过C—H⋯Cl相互作用聚集形成超分子层，这些超分子层进而堆叠构建出三维晶体结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/334f/2977589/5ff350825373/e-65-0m537-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/334f/2977589/c2b5d781359a/e-65-0m537-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/334f/2977589/5d050b7e08dd/e-65-0m537-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/334f/2977589/5ff350825373/e-65-0m537-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/334f/2977589/c2b5d781359a/e-65-0m537-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/334f/2977589/5d050b7e08dd/e-65-0m537-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/334f/2977589/5ff350825373/e-65-0m537-fig3.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.