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双（2,2'-联吡啶基）-1κN,N'；3κN,N'-双-（4-溴-2-甲酰基苯酚根）-1κO,O'；3κO,O'-双-[μ-2-（5-溴-2-氧化苄叉氨基）-乙烷磺酸根]-1:2κO:N,O；2:3κN,O:O-三水合三铜（II）

Bis(2,2'-bipyrid-yl)-1κN,N';3κN,N'-bis-(4-bromo-2-formyl-phenolato)-1κO,O';3κO,O'-bis-[μ-2-(5-bromo-2-oxidobenzylidene-amino)-ethane-sul-fon-ato]-1:2κO:N,O;2:3κN,O:O-tricopper(II) monohydrate.

作者信息

Zhang Ling

机构信息

Department of Chemistry, Lishui University, 323000 Lishui, Zhejiang, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 22;65(Pt 5):m552. doi: 10.1107/S1600536809014263.

DOI:10.1107/S1600536809014263
PMID:21583785
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977599/
Abstract

The title complex, [Cu(3)(C(9)H(8)BrNO(4)S)(2)(C(7)H(4)BrO(2))(2)(C(10)H(8)N(2))(2)]·H(2)O, lies on an inversion center located on the central Cu atom, which is four-coordinated in a square-planar geometry, whereas the outer Cu atoms related by symmetry are five-coordinated in a square-pyramidal geometry. The trinuclear mol-ecules, with an intramolecular Cu⋯Cu separation of 6.313 (3) Å, are linked to each other, forming a chain through O-H⋯O and O-H⋯Br hydrogen bonds involving the half-occupied water mol-ecule. Futhermore, weak C-H⋯O inter-actions link the chains to form a supra-molecular network.

摘要

标题配合物[Cu(3)(C(9)H(8)BrNO(4)S)(2)(C(7)H(4)BrO(2))(2)(C(10)H(8)N(2))(2)]·H(2)O位于中心铜原子上的一个反演中心上，该铜原子以平面正方形几何构型呈四配位，而通过对称相关的外部铜原子以正方锥几何构型呈五配位。三核分子的分子内铜⋯铜间距为6.313 (3) Å，它们相互连接，通过涉及半占据水分子的O-H⋯O和O-H⋯Br氢键形成一条链。此外，弱的C-H⋯O相互作用将这些链连接起来形成一个超分子网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce87/2977599/02e740a0fea3/e-65-0m552-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce87/2977599/48125b04d798/e-65-0m552-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce87/2977599/02e740a0fea3/e-65-0m552-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce87/2977599/48125b04d798/e-65-0m552-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce87/2977599/02e740a0fea3/e-65-0m552-fig2.jpg

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