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(20R,24R,25S)-3α,7α,12α,27-四乙酰氧基-24,26-环氧-5β-胆甾烷

(20R,24R,25S)-3α,7α,12α,27-Tetra-acet-oxy-24,26-ep-oxy-5β-cholestane.

作者信息

Ketuly Kamal Aziz, A Hadi A Hamid, Ng Seik Weng

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 10;65(Pt 5):o1026. doi: 10.1107/S160053680901188X.

DOI:10.1107/S160053680901188X
PMID:21583846
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977710/
Abstract

In the title anhydro-scymnol tetra-acetate, C(35)H(54)O(9), the fused chair conformation of the cyclo-hexane A/B ring junction is cis with a 5β-H configuration. The compound has a trimethyl-ene oxide ring at position 24,26 and four acetate groups at the 3α,7α,12α,27 positions.

摘要

在标题化合物无水司莫醇四乙酸酯(C(35)H(54)O(9))中,环己烷A/B环稠合处的椅式构象为顺式,具有5β-H构型。该化合物在24、26位有一个环氧丙烷环,在3α、7α、12α、27位有四个乙酸酯基团。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e2a/2977710/8ed1d2b2cf6c/e-65-o1026-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e2a/2977710/8ed1d2b2cf6c/e-65-o1026-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e2a/2977710/8ed1d2b2cf6c/e-65-o1026-fig1.jpg

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Study on the bile salt, sodium scymnol sulfate, from Rhizoprionodon acutus. II. The structures of scymnol, anhydroscymnol and sodium scymnol sulfate.
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