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(3R,6S,7aS)-3-苯基-6-(苯硫基)全氢吡咯并[1,2-c]恶唑-5-酮

(3R,6S,7aS)-3-Phenyl-6-(phenyl-sulfan-yl)perhydro-pyrrolo[1,2-c]oxazol-5-one.

作者信息

Gainsford Graeme J, Luxenburger Andreas, Woolhouse Anthony D

机构信息

Industrial Research Limited, PO Box 31-310, Lower Hutt, New Zealand.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 2;65(Pt 5):o943. doi: 10.1107/S1600536809011623.

DOI:10.1107/S1600536809011623
PMID:21583987
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977644/
Abstract

Mol-ecules of the title compound [systematic name: (2R,5S,7S)-2-phenyl-7-phenyl-sulfanyl-1-aza-3-oxa-bicyclo-[3.3.0]octan-8-one], C(18)H(17)NO(2)S, form high quality crystals even though they are only packed using C-H⋯O(carbon-yl) and weak C-H⋯S inter-actions. The dihedral angle between the aromatic rings is 85.53 (5)°. The fused rings adopt envelope and twist conformations.

摘要

标题化合物[系统名称：(2R,5S,7S)-2-苯基-7-苯基硫烷基-1-氮杂-3-氧杂双环[3.3.0]辛烷-8-酮]，C(18)H(17)NO(2)S的分子，即使它们仅通过C-H⋯O（羰基）和弱C-H⋯S相互作用堆积，也能形成高质量晶体。芳环之间的二面角为85.53 (5)°。稠环采用信封式和扭曲构象。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c16/2977644/57179a447018/e-65-0o943-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c16/2977644/be0260ed19e1/e-65-0o943-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c16/2977644/77147cc7ff42/e-65-0o943-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c16/2977644/57179a447018/e-65-0o943-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c16/2977644/be0260ed19e1/e-65-0o943-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c16/2977644/77147cc7ff42/e-65-0o943-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c16/2977644/57179a447018/e-65-0o943-fig3.jpg

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